It takes some time to find Dr. Michael
Duncan’s
office in the Chemistry Building on UGA’s South Campus just behind
Sanford Stadium. The building, which houses some of the finest scientists
in the country, seems at times like a maze of Legos, tucked in on the
natural slope of a hill and wandering for hundreds of yards east and
west along the ridge.
Once close, though, you can almost sense Duncan’s
place, because it reflects the personality of its occupant: laid-back,
friendly, generous and intensely
interested in work that has made him an internationally noted scientist, even
though he doesn’t turn 50 until Nov. 17. You will also know it is Duncan’s
office by the mildly hideous rattlesnake head—mouth open, fangs bared—sunk
in a plasticine paperweight on a filing cabinet. An ironic gift from his brother,
the snake is everything Duncan isn’t.
Mike—it seems stuffy and pretentious
to call someone this relaxed Dr. Duncan—sits
in his chair among a cluster of papers, notes of phone calls to return, and
hundreds of books that line his walls. He easily answers questions about
his life, but
it’s only when he starts talking about metals and lasers that he moves
forward to the edge of his chair.
Not many scientists have a genuine “eureka” moment
when they see a new field of study open before their eyes, but Mike did,
as a graduate student,
working with legendary chemist Richard Smalley at Rice University. Though
lasers had been around for a while by then, their use, which would become
pervasive
in society over the period of the last two decades, was still largely unknown
in the study of nanoparticles. Mike and a fellow graduate students were working
on a molecular beam experiment when—oops—they accidentally misaligned
the laser and vaporized part of the apparatus.
“We didn’t even know what we’d done
at first,” Mike recalls
with a laugh, “but then we looked at the mass spec and immediately
knew something was weird.”
Mass spectrometers are instruments that
separate charged particles so they can be studied when photographs
and graphs are made of the distributed
spectra of
the resulting “masses.” The signal Mike and his fellow
student saw on the mass spec was clearly one for metallic compounds,
so they
knew they’d
goofed and actually vaporized part of their equipment. The accident,
happily, led to a new way to produce large, regular molecules called
metal clusters, most
of which exist only for milliseconds and are mind-bogglingly hard to
study.
What began as a lab accident led to an entirely new
idea: shooting laser beams at metals and then studying the gaseous
metal clusters
that were
blasted off.
The Smalley group at Rice later used the same equipment and repeated
the experiments on carbon and discovered a form of the element called
carbon-60.
Shaped in
panels like the geodesic dome invented by architect Buckminster Fuller,
the C60 forms
were named “buckeyballs,” and the team that discovered
them was awarded the Nobel Prize for Chemistry in 1996.
Since he came
to UGA some 20 years ago, Mike has been on the cutting edge worldwide
in the study of metal clusters, and for at least a
decade, his
work on metal
carbides has placed him among the most sought-after chemists of
his generation for presentations and speeches, and his work has
drawn
interest and funding
from an astonishing range of federal agencies, including the National
Science Foundation,
the Department of Energy and the U. S. Air Force.
Not too shabby
for someone who didn’t even own a chemistry set as a boy.
Growing up in Greenville, S. C., Mike had the usual
preoccupations of a southern boy: sports and the outdoors. He also
loved playing
war games with bottle rockets with his brothers (“My wife was
appalled to find this out,” he laughs.), and once he participated
in a “court martial” that led to the brief hanging of
a younger brother by his feet from a tree limb. During WWII, his father,
had, in fact, been a guard during the Nuremburg Trials. His greatest
love, however, was baseball, which he played from boyhood sandlots
right through his undergraduate years at Furman University, where
he was a walk-on. He even pitched in fast-pitch softball during his
time as a postdoctoral fellow in Colorado.
“Nobody in my family was involved with science
at all,” he says.
His father was a salesman for a food brokerage company and his mother a homemaker.
Mike is the oldest of five, with one sister and three brothers (including a
pair of twins). “I guess I got interested because I just loved
to read. I remember in the first grade I read everything in sight,
and soon I was starting to read
a great deal about astronomy and space, which fascinated me.”
In high
school, an outstanding science teacher kindled his interest in the lab and,
as it turned out, in Furman, where her husband was a professor of
French. Mike discovered in physics and chemistry classes that these classic
underpinnings of the physical world utterly fascinated him. An exceptional
student, he had no trouble with the demands of these (or any other) courses,
so he was able to get a financial aid package, including a National Merit
Scholarship, to attend Furman—something that would have been difficult
in a family of five kids.
A self-described “typical nerd,” Mike
found tremendous satisfaction and challenge when he got to Furman, which
was not far from home in Greenville.
He was attracted to physical chemistry because he understood more than
most how things are put together. (He sometimes worked on cars and even,
incredibly,
designed and built a machine to evaporate metals while still a Furman
undergraduate.)
He met his future wife, Debbie, while at Furman,
and upon completion of his degree and, as he says, “dead
broke,” he
took a year off to work before being accepted to graduate school
at Rice. He was accepted at numerous
universities, but Debbie, by then his wife, wanted to be near a school
where she could pursue a master’s degree in social work.
The University of Houston, not far from Rice, had just such a
program,
so they packed everything
and moved to Texas.
While Furman was excellent for Mike, Rice was even
better, since Richard Smalley was already making a name for
himself, finding novel uses for
lasers. Though
Houston was far away from home, and he was unhappy for a short time,
Mike discovered soon enough that the Smalley lab was “heaven.” He
didn’t
work on metals right away, but after his accident vaporizing part
of the lab equipment, Mike knew the shape of his future. (He also
learned
to build his
own mass spectrometers, something he continues to this day.)
Work
in the Smalley lab was incredibly intense, and days were numbingly
long, typically from 8:30 in the morning until midnight. Having
finished all degree
requirements at Rice, he and Debbie left Houston in 1981 so Mike
could accept a postdoctoral fellowship at the Joint Institute for
Laboratory
Astrophysics
in Boulder, Colorado. While there, he applied for open faculty
positions back in his beloved Southeast, accepting a job as an assistant
professor
of chemistry
at UGA in 1983.
Georgia turned out to be a perfect match. It was
close to home in Greenville, and it offered an excellent start-up
package and an unmatched
instrument shop that never flinched at Mike’s increasingly complex
needs for equipment he designed and helped to build.
During his years
at UGA, Mike has taken his interest in the gas phase of metal clusters,
begun by accident at Rice, to such a level that
he’s one of
a handful of international authorities on the subject.
Overall, his research
program synthesizes and characterizes novel atomic and molecular “aggregates” containing
metals. These aggregates, which are called “clusters,” may
consist of only a few atoms of pure metal, mixtures of metals,
or metal compounds such as carbides or oxides. The
overall goal of the research is to understand how these atoms bond chemically—something
that remains unclear, in many cases, to science. And in 2000, he was part
of a startling discovery that is changing how science looks at the last
evolutionary stages of low-mass stars.
When low-mass stars called red supergiants
die, they fade away on a “wimpy” wind–or
so scientists thought. Mike’s research, co-authored with several
scientists from the University of Nijmegen in the Netherlands and published
in the prestigious
journal Science, suggested that the exact opposite may be true. These stars,
in fact, may die with a bang and not with a whimper. In fact, the study
may lead researchers to a new understanding of red supergiants, which are
studied
to resolve issues in nucleosynthesis, stellar structure, and the evolution
of stars.
“This discovery was really a gigantic surprise,” says
Mike. “One
of the beauties of doing fundamental science is that you never quite
know where it may lead.”
During their death throes, low mass
stars turn into red supergiants, which are more properly called
asymptotic giant branch stars or AGBs.
Actually
a stage of development rather than a specific kind of star, the AGB
phase is a relatively short stage during which low-mass stars become
their
brightest but experience heavy mass loss that leads them rapidly to
the planetary-nebula
phase and a final cooling to white dwarfs. (White dwarfs are extremely
hot,
Earth-sized objects that fade and cool for billions of years until
they become black, cold cinders.)
Scientists have been studying AGB
stars for a long time, but research has been accelerated in the
past few years through use of the Hubble
Space
Telescope and the European Space Agency’s Infrared Space
Satellite.
Mike’s involvement in the discovery was the kind
of scientific serendipity that often leads to unexpected breakthroughs.
His work took a huge step forward
due to collaboration with Dr. Gerard Meijer, whom he met at a scientific
meeting at Ohio State University in 1998, and Meijer’s colleagues
in The Netherlands.
“He was talking about the free-electron laser
called FELIX [Free-Electron Laser for Infrared Experiments] that
had been built at the his Institute, and
I happened to ask him if it had ever been used to study gas-phase
metal clusters,” says
Mike. “From that, our collaboration was born.”
There
are probably no more than 20 free-electron lasers in the world,
and only five in the U. S. (Priorities for use at the
U. S. machines
is largely
for
medical science or industrial applications.) FELIX is the
only one optimized for measuring infrared signals or “spectra” of
chemicals, and seemed a perfect match for the metal-cluster
experiments.
After meeting Meijer, Mike realized his team had a
free-electron laser, and he (Mike) had the pulsed molecular beam
machine
and experience working with
metal clusters, and they only needed to find a way to make
them work together.
Luckily, Meijer received at about that
time a large grant from the Dutch government, and so the team
in the Netherlands
was
able to
construct a copy of the molecular
beam machine that Duncan had been using to study metallic
clusters and
mate it with the free-electron laser.
The result was a machine that could detect the infrared
spectra of gas-phase metals and thus give important
clues to how
they are structured.
The
new apparatus worked beautifully, and when Mike visited
the lab in the summer
or 1998, the
team achieved the first direct infrared spectra of
these clusters ever done.
These spectra in themselves will likely
open a new era
in the study of how gas-phase metals are structured,
but a chance
meeting with
other Dutch scientists
initiated a startling discovery that led the research
from the lab to
the stars.
“These astronomers were visiting the FELIX lab
and hearing about work on polyaromatic hydrocarbons, which are important
in the composition of interstellar
space,” says Mike. “It just so happened
that our work on gas-phase metals was on a machine
nearby, and they asked what it was. Meijer and
another
scientist on the project, Gert von Helden, showed
them the machine and the spectra we had. That’s
when their jaws dropped.”
The astronomers,
led by Alexander Tielens of the University of
Groningen, realized immediately that
the infrared spectra
that
the group had
elicited from their
study of titanium carbide nanocrystals corresponded
almost exactly to spectra of unknown origin seen
again and again
in AGB stars.
The discovery created
a problem, however.
Meteorites containing micrometer-sized
graphite grains with embedded titanium carbide (TiC)
grains have been
discovered on Earth.
Isotopic analysis has
identified AGB stars as the birthplace of
these grains, though
there had been no direct
link. Astronomers believe that as AGB stars
begin to die, newly synthesized elements
such as TiC
are mixed
to the
surface where
they spread over
the galaxy in a wind, most often in the form
of stardust.
The problem lies in the fact
that the abundance of titanium in low-mass stars is so low that “high
densities are required just to get a high enough collision gains
to grow to the sizes observed in graphite stardust.” For
some 20 years, scientists have thought
that a so-called “superwind” phase
takes place when these stars exhibit a
dramatic loss of mass. But the superwind phase, despite its name,
has been
considered a relatively modest event in which
the star’s remaining stellar envelope
is blown away.
The identification of the
infrared spectra around AGB stars as
gas-phase titanium
carbide, however,
changes
that picture.
Because
of the low
amounts of titanium
in the stars and the apparent large amount
in the ejecta, the event creating them
must be caused
by something
that releases
tremendous
energy over
a relatively short period of time. Or
as the authors
wrote, “The TiC identification
suggests that rather than with a wimpy
wind, low -mass stars end their lives
with (almost) a bang.”
The study
of metal clusters in the Duncan lab,
of course, goes far beyond this
notable discovery,
and his colleagues
across
the country
and internationally
know his work quite well.
“Professor Duncan is a distinguished scientist,
nationally and internationally renowned for his work on clusters,” says
Dr. Kit Bowen, a professor at Johns Hopkins University in Baltimore. “Specifically,
he is the leader in studies involving the photodissociation of cluster
cations, and his work on
clusters has also had a substantial
impact in the quest to discover cluster-assembled materials. Also,
his infrared spectroscopic work at the free-electron laser in
Holland definitively characterized
`Metcars’, and
his work there on other metal carbide
systems is of fundamental astrophysical interest. Personally, he
is well known for his helpfulness,
often sharing his
data and techniques with his colleagues
around the world. He is an excellent colleague.”
The Duncan
lab buzzes with activity, but it’s not based on a type A
personality—which
Mike wouldn’t know if it
bit him—but on
his sheer drive and joy in the
discoveries that have led to dozens
of important
peer-reviewed papers.
Mike studied
neutral clusters first, and in
the Nineties, he and his
colleagues began to
study
cation particles
which are
significant
because
the researchers
can “size-select” the
particles, making them easier
to study.
By the mid-Nineties,
all of this
activity came together in a
rush of national
and international publicity.
His work
on so-called “nanocrystals” has
drawn interest from a wide
variety of groups and government
agencies.
The lab is also combining and
studying metal
ions and water molecules in
work that has earned increasing
plaudits
worldwide.
While Mike takes
his work seriously and speaks
of it with great
passion, he resolutely
refuses
to take himself
seriously
at
all. He laughs
easily, plays
tennis with Debbie, who is
a social worker in Athens,
and
their daughters
Allison,
a senior at Cedar
Shoals High
School in
Athens and Katherine,
a junior at UGA.
He also manages to cram in
time for golf and gardening.
He has
also maintained
a life-long love of music
that took off
when
he was a
member of the famed
Furman Singers as an undergraduate,
and
he is
now a tenor in a church choir.
He
often plays sports with
graduate students in chemistry,
and he
and his research
group take occasional
hikes together
in the
mountains.
He has been a
highly sought-after teacher and mentor in the
chemistry department
and has
acquired a
dazzling list
of
honors, including
being named a Fellow
in the American Physical
Society in 2001. His
research has earned
several
million
dollars in grants, too,
and he is
a senior editor
of the Journal
of Physical
Chemistry.
All of this
might go the head of someone else,
but
Mike remains
at heart a country
boy from
South Carolina, whose
fascination
with how
things
work has
led him from the fields
and woods to the stars.
